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Using of Compatibilizer for Improve Morphological Physical and Mechanical Properties of Biodegradable Plastic From Thermoplastic-strach-polyetylene Blends

机译:增容剂用于改善热塑性-稀-聚丙烯共混物可生物降解塑料的形态物理和力学性能的用途

摘要

Plastics as packaging material is very likely and used many time. However, plastics waste can pollute environment because plastic difficult to biodegrade by microorganism. Effort to reduce dependent plastic is develop plastic that environment friendly from renewable resources by blending method. Problems encountered in the manufacture of biodegradable plastic are not compatible between hydrophilic/polar and hydrophobic/non-polar materials. To improve the compatibility between the twomaterial blend were added materials such as compatibilizer. The purpose of this study was to determine the effect of compatibilizer on the physical and mechanical properties of biodegradable plastics made from thermoplastic starch (TPS) and Linear Low Density PolyEthylene (LLDPE) blend. This study consited two steps, namely preparation of thermoplastic starch, and manufacturing process of biodegradable plastic. The plastic properties observed included morphological structure, melt flow rate, density, temperature melting, and mechanical properties. Morphological structure of biodegradable plastic become compatible and homogeneous with the using of compatibilizer with the marked spread of TPS into the polymer matrix. Compatibilizer is able to mediate between two materials which have characteristics different that is LLDPE (hydrophobic) and TPS (hydrophilic). Using of a compatibilizer made biodegradable plastic more compatible, homogeneous and good mechanical properties. Compatibilizer can improve surface adhesivitas between LLDPE and TPS blend. The presence of MA-g-LLDPE resulted greater physical and mechanical properties of biodegradabel plastic than without compatibilizer.
机译:塑料作为包装材料非常有可能并且已经使用了很多次。然而,塑料废料会污染环境,因为塑料难以被微生物生物降解。减少依赖塑料的努力是通过混合方法开发可再生资源对环境无害的塑料。在生物可降解塑料的制造中遇到的问题在亲水/极性和疏水/非极性材料之间不兼容。为了改善两种材料混合物之间的相容性,添加了诸如相容剂的材料。这项研究的目的是确定增容剂对由热塑性淀粉(TPS)和线性低密度聚乙烯(LLDPE)共混物制成的可生物降解塑料的物理和机械性能的影响。这项研究包括两个步骤,即热塑性淀粉的制备和可生物降解塑料的制造工艺。观察到的塑性性能包括形态结构,熔体流动速率,密度,温度熔融和机械性能。可生物降解塑料的形态结构与相容剂的使用变得相容且均匀,TPS显着扩散到聚合物基质中。相容剂能够在两种材料之间进行介导,这两种材料具有不同的特性,即LLDPE(疏水性)和TPS(亲水性)。使用相容剂使可生物降解的塑料更加相容,均匀且具有良好的机械性能。相容剂可以改善LLDPE和TPS共混物之间的表面粘附力。 MA-g-LLDPE的存在导致了生物降解塑料的物理和机械性能高于没有增容剂的塑料。

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